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Volume 40
Main Index

Issue 01


Dynamic Processes Leading to Covalent Bond Formation for SN1 Reactions
Kevin S. Peters
pp 1–7 DOI: 10.1021/ar0681124
Polar Order by Rational Design:  Crystal Engineering with Parallel Beloamphiphile Monolayers
Rainer Glaser*
pp 9–17 DOI: 10.1021/ar0301633
Studies of Electronic Coupling and Mixed Valency in Metal−Metal Quadruply Bonded Complexes Linked by Dicarboxylate and Closely Related Ligands
Malcolm H. Chisholm and Nathan J. Patmore
pp 19–27 DOI: 10.1021/ar068100i
Organization of Zeolite Microcrystals for Production of Functional Materials
Kyung Byung Yoon
pp 29–40 DOI: 10.1021/ar000119c
Metal-Based Turn-On Fluorescent Probes for Sensing Nitric Oxide
Mi Hee Lim and Stephen J. Lippard
pp 41–51 DOI: 10.1021/ar950149t
Plasmonic Nanostructures:  Artificial Molecules
Hui Wang, Daniel W. Brandl, Peter Nordlander, and Naomi J. Halas
pp 53–62 DOI: 10.1021/ar0401045
Modular and Dynamic Functionalization of Polymeric Scaffolds
Clinton R. South, Caroline Burd, and Marcus Weck
pp 63–74 DOI: 10.1021/ar0500160
Ultrafast 2D IR Vibrational Echo Spectroscopy
Junrong Zheng, Kyungwon Kwak, and M. D. Fayer
pp 75–83 DOI: 10.1021/ar068010d
Effect of Carboxylate-Binding Mode on Metal Binding/Selectivity and Function in Proteins
Todor Dudev and Carmay Lim,
pp 85–93 DOI: 10.1021/ar068181i

Issue 02


Construction, Substitution, and Sorting of Metallo-organic Structures via Subcomponent Self-Assembly
Jonathan R. Nitschke
pp 103–112 DOI: 10.1021/ar068185n
Theoretical Analysis of the Rotational Barrier of Ethane
Yirong Mo and Jiali Gao
pp 113–119 DOI: 10.1021/ar068073w
Chromogenic Cross-Link Formation in Green Fluorescent Protein
Rebekka M. Wachter
pp 120–127 DOI: 10.1021/ar040086r
Photoinduced-Electron-Transfer Chemistry:  From Studies on PET Processes to Applications in Natural Product Synthesis
Axel G. Griesbeck, Norbert Hoffmann, and Klaus-dieter Warzecha
pp 128–140 DOI: 10.1021/ar068148w
Synthesis and Properties of Size-Expanded DNAs:  Toward Designed, Functional Genetic Systems
Andrew T. Krueger, Haige Lu, Alex H. F. Lee, and Eric T. Kool
pp 141–150 DOI: 10.1021/ar068200o
Chemistry of the Hexahydropyrrolo[2,3-b]indoles:  Configuration, Conformation, Reactivity, and Applications in Synthesis
David Crich and Abhisek Banerjee
pp 151–161 DOI: 10.1021/ar050175j
Solvothermal in Situ Metal/Ligand Reactions:  A New Bridge between Coordination Chemistry and Organic Synthetic Chemistry
Xiao-Ming Chen and Ming-Liang Tong
pp 162–170 DOI: 10.1021/ar068084p

Issue 03


Functional Roles of the Heme Architecture and Its Environment in Tetraheme Cytochrome c
Hideo Akutsu and Yuki Takayama
pp 171–178 DOI: 10.1021/ar030262g
Catalytic Enantioselective Conjugate Addition with Grignard Reagents
Fernando López, Adriaan J. Minnaard, and Ben L. Feringa
pp 179–188 DOI: 10.1021/ar0501976
Four-Center Carbon−Carbon Bonding
Joel S. Miller, Juan J. Novoa
pp 189–196 DOI: 10.1021/ar068175m
Lone Pair−Aromatic Interactions:  To Stabilize or Not to Stabilize
Martin Egli and Sanjay Sarkhel
pp 197–205 DOI: 10.1021/ar068174u
NMR Structure Determination of Protein−Ligand Complexes by Lanthanide Labeling
Guido Pintacuda, Michael John, Xun-Cheng Su, and Gottfried Otting
pp 206–212 DOI: 10.1021/ar050087z
Nonlocal Electronic Distribution in Metallic Clusters:  A Critical Examination of Aromatic Stabilization
Ayan Datta, Sairam S. Mallajosyula, and Swapan K. Pati
pp 213–221 DOI: 10.1021/ar0682738
Solvent Effects on the Rates and Mechanisms of Reaction of Phenols with Free Radicals
Grzegorz Litwinienko and K. U. Ingold
pp 222–230 DOI: 10.1021/ar0682029
Structural and Electron Paramagnetic Resonance (EPR) Studies of Mononuclear Molybdenum Enzymes from Sulfate-Reducing Bacteria
Carlos D. Brondino, María G. Rivas, Maria J. Romão, José J. G. Moura, and Isabel Moura
pp 231–231 DOI: 10.1021/ar600049k

Issue 04


Evolution of Organo-Cyanometallate Cages:  Supramolecular Architectures and New Cs+-Specific Receptors
Julie L. Boyer, Matthew L. Kuhlman, and Thomas B. Rauchfuss
pp 233–242 DOI: 10.1021/ar050215j
The Dance of Molecules:  New Dynamical Perspectives on Highly Excited Molecular Vibrations
Michael E. Kellman and Vivian Tyng
pp 243–250 DOI: 10.1021/ar000153r
New Insights into the Oxidative Electrochemistry of Vitamin E
Richard D. Webster
pp 251–257 DOI: 10.1021/ar068182a
The Chromophore Structural Changes during the Photocycle of Phytochrome:  A Combined Resonance Raman and Quantum Chemical Approach
Maria Andrea Mroginski, Daniel H. Murgida, and Peter Hildebrandt
pp 258–266 DOI: 10.1021/ar6000523
Bioinorganic Chemistry of Bismuth and Antimony:  Target Sites of Metallodrugs
Ruiguang Ge and Hongzhe Sun
pp 267–274 DOI: 10.1021/ar600001b
Organotrifluoroborates:  Protected Boronic Acids That Expand the Versatility of the Suzuki Coupling Reaction
Gary A. Molander and Noel Ellis
pp 275–286 DOI: 10.1021/ar050199q
Molecular Packing and Symmetry of Two-Dimensional Crystals
Katherine E. Plass, Adam L. Grzesiak, and Adam J. Matzger
pp 287–293 DOI: 10.1021/ar0500158
Energetics of Electron-Transfer Reactions in Soft Condensed Media
Dmitry V. Matyushov
pp 294–301 DOI: 10.1021/ar7000167

Issue 05


Radicals Masquerading as Electrophiles: Dual Orbital Effects in Nitrogen-Philic Acyl Radical Cyclization and Related Addition Reactions
Carl H. Schiesser, Uta Wille, Hiroshi Matsubara and Ilhyong Ryu
pp 303–313 DOI: 10.1021/ar600015v
Smart Nanomaterials Inspired by Biology: Dynamic Assembly of Error-Free Nanomaterials in Response to Multiple Chemical and Biological Stimuli
Yi Lu and Juewen Liu
pp 315–323 DOI: 10.1021/ar600053g
How Do Enzymes Activate Oxygen without Inactivating Themselves?
Judith P. Klinman
pp 325–333 DOI: 10.1021/ar6000507
Nanoparticle Interaction with Biological Membranes: Does Nanotechnology Present a Janus Face?
Pascale R. Leroueil, Seungpyo Hong, Almut Mecke, James R. Baker, Jr., Bradford G. Orr and Mark M. Banaszak Holl
pp 335–342 DOI: 10.1021/ar600012y
Inorganic Sensing Using Organofunctional Sol–Gel Materials
Nathan A. Carrington and Zi-Ling Xue
pp 343–350 DOI: 10.1021/ar600017w
Molecular Interactions in Amphiphilic Assemblies: Theoretical Perspective
Nilashis Nandi and Dieter Vollhardt
pp 351–360 DOI: 10.1021/ar600057b
Photo-induced Valence Tautomerism in Co Complexes
Osamu Sato, Aili Cui, Ryotaro Matsuda, Jun Tao and Shinya Hayami
pp 361–369 DOI: 10.1021/ar600014m
Transition-Metal Complexes of Expanded Porphyrins
Jonathan L. Sessler and Elisa Tomat
pp 371–379 DOI: 10.1021/ar600006n

Issue 06


Mild and Neutral Deprotections Catalyzed by Cerium(IV) Ammonium Nitrate
Nuno Maulide, Jean-Christophe Vanherck, Arnaud Gautier and István E. Markó
pp 381–392 DOI: 10.1021/ar600062b
Langmuir–Blodgett Patterning: A Bottom–Up Way To Build Mesostructures over Large Areas
Xiaodong Chen, Steven Lenhert, Michael Hirtz, Nan Lu, Harald Fuchs and Lifeng Chi
pp 393–401 DOI: 10.1021/ar600019r
Fluorescent Hybridization Probes for Sensitive and Selective DNA and RNA Detection
Angel A. Martí, Steffen Jockusch, Nathan Stevens, Jingyue Ju and Nicholas J. Turro
pp 402–409 DOI: 10.1021/ar600013q
Stable Silyl, Germyl, and Stannyl Cations, Radicals, and Anions: Heavy Versions of Carbocations, Carbon Radicals, and Carbanions
Vladimir Ya. Lee and Akira Sekiguchi
pp 410–419 DOI: 10.1021/ar6000473
Nanodimensional Organostannoxane Molecular Assemblies
Vadapalli Chandrasekhar, Kandasamy Gopal and Pakkirisamy Thilagar
pp 420–434 DOI: 10.1021/ar600061f
Anion Binding Involving π-Acidic Heteroaromatic Rings
Patrick Gamez, Tiddo J. Mooibroek, Simon J. Teat and Jan Reedijk
pp 435–444 DOI: 10.1021/ar7000099
Shall We Dance? How A Multicopper Oxidase Chooses Its Electron Transfer Partner
Liliana Quintanar, Christopher Stoj, Alexander B. Taylor, P. John Hart, Daniel J. Kosman and Edward I. Solomon
pp 445–452 DOI: 10.1021/ar600051a
Catalysis of Stannane-Mediated Radical Chain Reactions by Benzeneselenol
David Crich, Daniel Grant, Venkataramanan Krishnamurthy and Mitesh Patel
pp 453–463 DOI: 10.1021/ar600020v

Issue 07


Dioxygen Activation by Metalloenzymes and Models
Wonwoo Nam
pp 465–465 DOI: 10.1021/ar700131d
Substrate Trafficking and Dioxygen Activation in Bacterial Multicomponent Monooxygenases
Leslie J. Murray and Stephen J. Lippard
pp 466–474 DOI: 10.1021/ar600040e
Finding Intermediates in the O2 Activation Pathways of Non-Heme Iron Oxygenases
E. G. Kovaleva, M. B. Neibergall, S. Chakrabarty and J. D. Lipscomb
pp 475–483 DOI: 10.1021/ar700052v
Non-Heme Fe(IV)–Oxo Intermediates
Carsten Krebs, Danica Galonić Fujimori, Christopher T. Walsh and J. Martin Bollinger, Jr.
pp 484–492 DOI: 10.1021/ar700066p
The Road to Non-Heme Oxoferryls and Beyond
Lawrence Que, Jr.
pp 493–500 DOI: 10.1021/ar700024g
Understanding How the Thiolate Sulfur Contributes to the Function of the Non-Heme Iron Enzyme Superoxide Reductase
Julie A. Kovacs and Lisa M. Brines
pp 501–509 DOI: 10.1021/ar600059h
Dioxygen Activation at Non-Heme Iron: Insights from Rapid Kinetic Studies
Ivan V. Korendovych, Sergey V. Kryatov and Elena V. Rybak-Akimova
pp 510–521 DOI: 10.1021/ar600041x
High-Valent Iron(IV)–Oxo Complexes of Heme and Non-Heme Ligands in Oxygenation Reactions
Wonwoo Nam
pp 522–531 DOI: 10.1021/ar700027f
Reactivity of High-Valent Iron–Oxo Species in Enzymes and Synthetic Reagents: A Tale of Many States
Sason Shaik, Hajime Hirao and Devesh Kumar
pp 532–542 DOI: 10.1021/ar600042c
Role of Proton-Coupled Electron Transfer in O–O Bond Activation
Joel Rosenthal and Daniel G. Nocera
pp 543–553 DOI: 10.1021/ar7000638
Reactivities of Oxo and Peroxo Intermediates Studied by Hemoprotein Mutants
Yoshihito Watanabe, Hiroshi Nakajima and Takafumi Ueno
pp 554–562 DOI: 10.1021/ar600046a
Heme–Copper/Dioxygen Adduct Formation, Properties, and Reactivity
Eduardo E. Chufán, Simona C. Puiu and Kenneth D. Karlin
pp 563–572 DOI: 10.1021/ar700031t
Structural and Mechanistic Insights into Methane Oxidation by Particulate Methane Monooxygenase
Ramakrishnan Balasubramanian and Amy C. Rosenzweig
pp 573–580 DOI: 10.1021/ar700004s
O2 and N2O Activation by Bi-, Tri-, and Tetranuclear Cu Clusters in Biology
Edward I. Solomon, Ritimukta Sarangi, Julia S. Woertink, Anthony J. Augustine, Jungjoo Yoon and Somdatta Ghosh
pp 581–591 DOI: 10.1021/ar600060t
Monooxygenase Activity of Type 3 Copper Proteins
Shinobu Itoh and Shunichi Fukuzumi
pp 592–600 DOI: 10.1021/ar6000395
Mononuclear Cu–O2 Complexes: Geometries, Spectroscopic Properties, Electronic Structures, and Reactivity
Christopher J. Cramer and William B. Tolman
pp 601–608 DOI: 10.1021/ar700008c
Ligand Effects on Dioxygen Activation by Copper and Nickel Complexes: Reactivity and Intermediates
Masatatsu Suzuki
pp 609–617 DOI: 10.1021/ar600048g
Dioxygen Activation at Monovalent Nickel
Matthew T. Kieber-Emmons and Charles G. Riordan
pp 618–625 DOI: 10.1021/ar700043n
Corrolazines: New Frontiers in High-Valent Metalloporphyrinoid Stability and Reactivity
David P. Goldberg
pp 626–634 DOI: 10.1021/ar700039y

Issue 08


Interface-Mediated Growth of Monodispersed Nanostructures
Xun Wang, Qing Peng and Yadong Li
pp 635–643 DOI: 10.1021/ar600007y
π-Organogels of Self-Assembled p-Phenylenevinylenes: Soft Materials with Distinct Size, Shape, and Functions
Ayyappanpillai Ajayaghosh and Vakayil K. Praveen
pp 644–656 DOI: 10.1021/ar7000364
Interweaving Anion Templation
Michael D. Lankshear and Paul D. Beer
pp 657–668 DOI: 10.1021/ar7000217
Solvent-Mediated Proton Transfer in Catalysis by Carbonic Anhydrase
David N. Silverman and Robert McKenna
pp 669–675 DOI: 10.1021/ar7000588
Metal Unsaturation and Ligand Hemilability in Suzuki Coupling
Zhiqiang Weng, Shihui Teo and T. S. Andy Hor
pp 676–684 DOI: 10.1021/ar600003h
Self-Assembly of Inorganic Nanocrystals: Fabrication and Collective Intrinsic Properties
M.-P. Pileni
pp 685–693 DOI: 10.1021/ar6000582
Crystalline Host–Guest Assemblies of Steroidal and Related Molecules: Diversity, Hierarchy, and Supramolecular Chirality
Mikiji Miyata, Norimitsu Tohnai and Ichiro Hisaki
pp 694–702 DOI: 10.1021/ar700017a
Annulenylenes, Annulynes, and Annulenes
Cheryl D. Stevenson
pp 703–711 DOI: 10.1021/ar600067n
Synthetic Development and Chemical Reactivity of Transition-Metal Silylene Complexes
Rory Waterman, Paul G. Hayes and T. Don Tilley
pp 712–719 DOI: 10.1021/ar700028b
Slow Solvation Dynamics of a Water–Nitrobenzene System
Greg Moakes and Jiri Janata
pp 720–728 DOI: 10.1021/ar700067e

Issue 09


Sol–Gel Chemistry and Materials
Bruce Dunn and Jeffrey I. Zink
pp 729–729 DOI: 10.1021/ar700178b
Organically Modified Transition Metal Alkoxides: Chemical Problems and Structural Issues on the Way to Materials Syntheses
Ulrich Schubert
pp 730–737 DOI: 10.1021/ar600036x
Advanced Solid State NMR Techniques for the Characterization of Sol–Gel-Derived Materials
Christian Bonhomme, Cristina Coelho, Niki Baccile, Christel Gervais, Thierry Azaïs and Florence Babonneau
pp 738–746 DOI: 10.1021/ar600030j
Molecules in Glass: Probes, Ordered Assemblies, and Functional Materials
Bruce Dunn and Jeffrey I. Zink
pp 747–755 DOI: 10.1021/ar700033b
Molecularly Imprinted Xerogels as Platforms for Sensing
Ellen L. Holthoff and Frank V. Bright
pp 756–767 DOI: 10.1021/ar700087t
The Induction of Chirality in Sol–Gel Materials
Sharon Marx and David Avnir
pp 768–776 DOI: 10.1021/ar6000236
Electrochemistry: An Important Tool To Study and Create New Sol–Gel-Derived Materials
Maryanne M. Collinson
pp 777–783 DOI: 10.1021/ar600029p
Harnessing the Sol–Gel Process for the Assembly of Non-Silicate Mesostructured Oxide Materials
Shannon W. Boettcher, Jie Fan, Chia-Kuang Tsung, Qihui Shi and Galen D. Stucky
pp 784–792 DOI: 10.1021/ar6000389
Nonaqueous Sol–Gel Routes to Metal Oxide Nanoparticles
Markus Niederberger
pp 793–800 DOI: 10.1021/ar600035e
Sol–Gel Methods for the Assembly of Metal Chalcogenide Quantum Dots
Indika U. Arachchige and Stephanie L. Brock
pp 801–809 DOI: 10.1021/ar600028s
Chemical Routes in the Synthesis of Nanomaterials Using the Sol–Gel Process
John D. Mackenzie and Eric P. Bescher
pp 810–818 DOI: 10.1021/ar7000149
Aqueous Silicates in Biological Sol–Gel Applications: New Perspectives for Old Precursors
Thibaud Coradin and Jacques Livage
pp 819–826 DOI: 10.1021/ar068129m
Biofriendly Sol–Gel Processing for the Entrapment of Soluble and Membrane-Bound Proteins: Toward Novel Solid-Phase Assays for High-Throughput Screening
John D. Brennan
pp 827–835 DOI: 10.1021/ar6000268
Cell-Directed Assembly of Bio/Nano Interfaces—A New Scheme for Cell Immobilization
Helen K. Baca, Eric Carnes, Seema Singh, Carlee Ashley, Deanna Lopez and C. Jeffrey Brinker
pp 836–845 DOI: 10.1021/ar600027u
Synthesis and Functionalization of a Mesoporous Silica Nanoparticle Based on the Sol–Gel Process and Applications in Controlled Release
Brian G. Trewyn, Igor I. Slowing, Supratim Giri, Hung-Ting Chen and Victor S.-Y. Lin
pp 846–853 DOI: 10.1021/ar600032u
Architectural Design, Interior Decoration, and Three-Dimensional Plumbing en Route to Multifunctional Nanoarchitectures
Jeffrey W. Long and Debra R. Rolison
pp 854–862 DOI: 10.1021/ar6000445
Sol–Gel with Phase Separation. Hierarchically Porous Materials Optimized for High-Performance Liquid Chromatography Separations
Kazuki Nakanishi and Nobuo Tanaka
pp 863–873 DOI: 10.1021/ar600034p
Three-Dimensional Core-Shell Superstructures: Mechanically Strong Aerogels
Nicholas Leventis
pp 874–884 DOI: 10.1021/ar600033s
Glycol-Modified Silanes: Novel Possibilities for the Synthesis of Hierarchically Organized (Hybrid) Porous Materials
Sarah Hartmann, Doris Brandhuber and Nicola Hüsing
pp 885–894 DOI: 10.1021/ar6000318
Functionalized Sol–Gel Coatings for Optical Applications
Anne-Laure Pénard, Thierry Gacoin and Jean-Pierre Boilot
pp 895–902 DOI: 10.1021/ar600025j
Photo-imageable Sol–Gel Hybrid Materials for Simple Fabrication of Micro-optical Elements
Dong Jun Kang and Byeong-Soo Bae
pp 903–912 DOI: 10.1021/ar6000439
Sol–Gel-Derived Spheres for Spherical Microcavity
Shuichi Shibata, Tetsuji Yano and Hiroyo Segawa
pp 913–920 DOI: 10.1021/ar600037c

Issue 10


Selective Fluoroalkylations with Fluorinated Sulfones, Sulfoxides, and Sulfides
G. K. Surya Prakash and Jinbo Hu
pp 921–930 DOI: 10.1021/ar700149s
New Organic Chemistry of Sulfur Dioxide
Pierre Vogel, Ma̅ris Turks, Laure Bouchez, Dean Marković, Adrián Varela-Álvarez and José Ángel Sordo
pp 931–942 DOI: 10.1021/ar700096h
Catalytic Coupling of sp2- and sp-Hybridized Carbon–Hydrogen Bonds with Vinylmetalloid Compounds
Bogdan Marciniec
pp 943–952 DOI: 10.1021/ar700116f
Visual Methods for Interpreting Optical Nonlinearity at the Molecular Level
Ronald D. Wampler, Andrew J. Moad, Charles W. Moad, Randy Heiland and Garth J. Simpson
pp 953–960 DOI: 10.1021/ar600055t
Manifestations of Stereoelectronic Interactions in 1JC–H One-Bond Coupling Constants
Eusebio Juaristi and Gabriel Cuevas
pp 961–970 DOI: 10.1021/ar6000186
New Catalytic Reactions of Oxa- and Azabicyclic Alkenes
Dinesh Kumar Rayabarapu and Chien-Hong Cheng
pp 971–983 DOI: 10.1021/ar600021z
Performing Organic Chemistry with Inorganic Compounds: Electrophilic Reactivity of Selected Nitrosyl Complexes
Fabio Doctorovich and Florencia Di Salvo
pp 985–993 DOI: 10.1021/ar6000457
Molecular Views of Physical Adsorption Inside and Outside of Single-Wall Carbon Nanotubes
Petro Kondratyuk and John T. Yates, Jr.
pp 995–1004 DOI: 10.1021/ar700013c
Ionothermal Synthesis of Zeolites, Metal–Organic Frameworks, and Inorganic–Organic Hybrids
Emily R. Parnham and Russell E. Morris
pp 1005–1013 DOI: 10.1021/ar700025k
Electronic Communication in Tetrathiafulvalene (TTF)/C60 Systems: Toward Molecular Solar Energy Conversion Materials?
Nazario Martín, Luis Sánchez, María Ángeles Herranz, Beatriz Illescas and Dirk M. Guldi
pp 1015–1024 DOI: 10.1021/ar700026t
Tagged Small Molecule Library Approach for Facilitated Chemical Genetics
Young-Hoon Ahn and Young-Tae Chang
pp 1025–1033 DOI: 10.1021/ar700030k
Aromatic Iridacycles
John R. Bleeke
pp 1035–1047 DOI: 10.1021/ar700071p
Rational Design of Minimal Artificial Diels–Alderases Based on the Copper(II) Cation–Aromatic π Attractive Interaction
Kazuaki Ishihara, Makoto Fushimi and Matsujiro Akakura
pp 1049–1055 DOI: 10.1021/ar700083a
A Journey in Structure-Based Drug Discovery: From Designed Peptides to Protein Surface Topomimetics as Antibiotic and Antiangiogenic Agents
Ruud P. M. Dings and Kevin H. Mayo
pp 1057–1065 DOI: 10.1021/ar700086k
Synthesis of Silver Nanostructures with Controlled Shapes and Properties
Benjamin Wiley, Yugang Sun and Younan Xia
pp 1067–1076 DOI: 10.1021/ar7000974

Issue 11


Ionic Liquids
Robin D. Rogers and Gregory A. Voth
pp 1077–1078 DOI: 10.1021/ar700221n
Ionic Liquids in Separations
Xinxin Han and Daniel W. Armstrong
pp 1079–1086 DOI: 10.1021/ar700044y
Molecular Solutes in Ionic Liquids: A Structural Perspective
Agílio A. H. Pádua, Margarida F. Costa Gomes and José N. A. Canongia Lopes
pp 1087–1096 DOI: 10.1021/ar700050q
Room-Temperature Ionic Liquids: Slow Dynamics, Viscosity, and the Red Edge Effect
Zhonghan Hu and Claudio J. Margulis
pp 1097–1105 DOI: 10.1021/ar700046m
Ionic Liquids: The Link to High-Temperature Molten Salts?
Sherif Zein El Abedin and Frank Endres
pp 1106–1113 DOI: 10.1021/ar700049w
Accounting for the Unique, Doubly Dual Nature of Ionic Liquids from a Molecular Thermodynamic and Modeling Standpoint
Luís Paulo N. Rebelo, José N. Canongia Lopes, José M. S. S. Esperança, Henrique J. R. Guedes, Joanna Łachwa, Vesna Najdanovic-Visak and Zoran P. Visak
pp 1114–1121 DOI: 10.1021/ar7000556
Amino Acid Ionic Liquids
Hiroyuki Ohno and Kenta Fukumoto
pp 1122–1129 DOI: 10.1021/ar700053z
Solvation, Solute Rotation and Vibration Relaxation, and Electron-Transfer Reactions in Room-Temperature Ionic Liquids
Youngseon Shim, Daun Jeong, Swati Manjari, Moo Young Choi and Hyung J. Kim
pp 1130–1137 DOI: 10.1021/ar700061r
Simulations of Ionic Liquids, Solutions, and Surfaces
Ruth M. Lynden-Bell, Mario G. Del Pópolo, Tristan G. A. Youngs, Jorge Kohanoff, Christof G. Hanke, Jason B. Harper and Carlos C. Pinilla
pp 1138–1145 DOI: 10.1021/ar700065s
Structure and Solvation in Ionic Liquids
Christopher Hardacre, John D. Holbrey, Mark Nieuwenhuyzen and Tristan G. A. Youngs
pp 1146–1155 DOI: 10.1021/ar700068x
Clusters, Liquids, and Crystals of Dialkyimidazolium Salts. A Combined Perspective from ab Initio and Classical Computer Simulations
Mario G. Del Pópolo, Jorge Kohanoff, Ruth M. Lynden-Bell and Carlos Pinilla
pp 1156–1164 DOI: 10.1021/ar700069c
Ionic Liquids in Electrochemical Devices and Processes: Managing Interfacial Electrochemistry
Douglas R. MacFarlane, Maria Forsyth, Patrick C. Howlett, Jennifer M. Pringle, Jiazeng Sun, Gary Annat, Wayne Neil and Ekaterina I. Izgorodina
pp 1165–1173 DOI: 10.1021/ar7000952
Local Structure Formation in Alkyl-imidazolium-Based Ionic Liquids as Revealed by Linear and Nonlinear Raman Spectroscopy
Koichi Iwata, Hajime Okajima, Satyen Saha and Hiro-o Hamaguchi
pp 1174–1181 DOI: 10.1021/ar700074c
The Second Evolution of Ionic Liquids: From Solvents and Separations to Advanced Materials—Energetic Examples from the Ionic Liquid Cookbook
Marcin Smiglak, Andreas Metlen and Robin D. Rogers
pp 1182–1192 DOI: 10.1021/ar7001304
Understanding Ionic Liquids through Atomistic and Coarse-Grained Molecular Dynamics Simulations
Yanting Wang, Wei Jiang, Tianying Yan and Gregory A. Voth
pp 1193–1199 DOI: 10.1021/ar700160p
Atomistic Simulation of the Thermodynamic and Transport Properties of Ionic Liquids
Edward J. Maginn
pp 1200–1207 DOI: 10.1021/ar700163c
Solubility of CO2, CH4, C2H6, C2H4, O2, and N2 in 1-Hexyl-3-methylpyridinium Bis(trifluoromethylsulfonyl)imide: Comparison to Other Ionic Liquids
Jessica L. Anderson, JaNeille K. Dixon and Joan F. Brennecke
pp 1208–1216 DOI: 10.1021/ar7001649
Intermolecular Dynamics, Interactions, and Solvation in Ionic Liquids
Edward W. Castner, Jr., James F. Wishart and Hideaki Shirota
pp 1217–1227 DOI: 10.1021/ar700169g
Parallel Developments in Aprotic and Protic Ionic Liquids: Physical Chemistry and Applications
C. Austen Angell, Nolene Byrne and Jean-Philippe Belieres
pp 1228–1236 DOI: 10.1021/ar7001842

Issue 12


Hydrogenation and Transfer Hydrogenation
Michael J. Krische, Yongkui Sun
pp 1237–1237 DOI: 10.1021/ar700250e
Pioneering Perspectives on Asymmetric Hydrogenation
William S. Knowles, Ryoji Noyori
pp 1238–1239 DOI: 10.1021/ar7000809
From a Chiral Switch to a Ligand Portfolio for Asymmetric Catalysis
Hans-Ulrich Blaser, Benoît Pugin, Felix Spindler and Marc Thommen
pp 1240–1250 DOI: 10.1021/ar7001057
Ligands for Practical Rhodium-Catalyzed Asymmetric Hydroformylation
Jerzy Klosin and Clark R. Landis
pp 1251–1259 DOI: 10.1021/ar7001039
Biocatalytic Reductions: From Lab Curiosity to “First Choice”
Stefaan M. A. De Wildeman, Theo Sonke, Hans E. Schoemaker and Oliver May
pp 1260–1266 DOI: 10.1021/ar7001073
Asymmetric Hydrogenation Using Monodentate Phosphoramidite Ligands
Adriaan J. Minnaard, Ben L. Feringa, Laurent Lefort and Johannes G. de Vries
pp 1267–1277 DOI: 10.1021/ar7001107
Developing Chiral Ligands for Asymmetric Hydrogenation
Weicheng Zhang, Yongxiang Chi and Xumu Zhang
pp 1278–1290 DOI: 10.1021/ar7000028
Industrial-Scale Synthesis and Applications of Asymmetric Hydrogenation Catalysts
Nicholas B. Johnson, Ian C. Lennon, Paul H. Moran and James A. Ramsden
pp 1291–1299 DOI: 10.1021/ar700114k
Asymmetric Transfer Hydrogenation of Ketones with Bifunctional Transition Metal-Based Molecular Catalysts
Takao Ikariya and A. John Blacker
pp 1300–1308 DOI: 10.1021/ar700134q
Hydrogenation Processes in the Synthesis of Perfumery Ingredients
Lionel A. Saudan
pp 1309–1319 DOI: 10.1021/ar700140m
Unlocking the Potential of Asymmetric Hydrogenation at Merck
C. Scott Shultz and Shane W. Krska
pp 1320–1326 DOI: 10.1021/ar700141v
Enantioselective Organocatalytic Transfer Hydrogenation Reactions using Hantzsch Esters
Stéphane G. Ouellet, Abbas M. Walji and David W. C. Macmillan
pp 1327–1339 DOI: 10.1021/ar7001864
[(Bisphosphine) Ru(II) Diamine] Complexes in Asymmetric Hydrogenation: Expanding the Scope of the Diamine Ligand
William P. Hems, Michelle Groarke, Antonio Zanotti-Gerosa and Gabriela A. Grasa
pp 1340–1347 DOI: 10.1021/ar7000233
Cinchona-Modified Platinum Catalysts: From Ligand Acceleration to Technical Processes
Hans-Ulrich Blaser and Martin Studer
pp 1348–1356 DOI: 10.1021/ar700088f
Asymmetric Hydrogenation of Heteroaromatic Compounds
Yong-Gui Zhou
pp 1357–1366 DOI: 10.1021/ar700094b
Asymmetric Hydrogenation of Prochiral Amino Ketones to Amino Alcohols for Pharmaceutical Use
Franz Dietrich Klingler,
pp 1367–1376 DOI: 10.1021/ar700100e
Construction of a Chiral Central Nervous System (CNS)-Active Aminotetralin Drug Compound Based on a Synthesis Strategy Using Multitasking Properties of ( S)-1-Phenylethylamine
Hans-Jürgen Federsel, , Martin Hedberg, , Fredrik R. Qvarnström, , Magnus P. T. Sjögren, and Wei Tian,
pp 1377–1384 DOI: 10.1021/ar700102c
Developments in Asymmetric Hydrogenation from an Industrial Perspective
Hideo Shimizu, , Izuru Nagasaki, , Kazuhiko Matsumura, , Noboru Sayo, and Takao Saito,
pp 1385–1393 DOI: 10.1021/ar700101x
Enantiomerically Enriched Allylic Alcohols and Allylic Amines via C–C Bond-Forming Hydrogenation: Asymmetric Carbonyl and Imine Vinylation
Eduardas Skucas, Ming-Yu Ngai, Venukrishnan Komanduri and Michael J. Krische
pp 1394–1401 DOI: 10.1021/ar7001123
Iridium-Catalyzed Asymmetric Hydrogenation of Olefins
Stephen J. Roseblade and Andreas Pfaltz
pp 1402–1411 DOI: 10.1021/ar700113g
Advances in the Enzymatic Reduction of Ketones
Jeffrey C. Moore, David J. Pollard, Birgit Kosjek and Paul N. Devine
pp 1412–1419 DOI: 10.1021/ar700167a